SpectraSim Documentation
Parameter · 04 Material

Water-vapour mole fraction

material.humid.x_h2o Step 04 · Material

The mole fraction of water vapour in humid air, used as entered. Dry air makes up the rest in its standard composition.

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Theory

The humid gas is an ideal-gas mixture: every dry-air species keeps its share of the dry part, scaled by 1−xH2O1 - x_{H_2O}, and water vapour takes xH2Ox_{H_2O}. The molar mass, the heat-capacity polynomial and therefore the density, the ratio of specific heats and the speed of sound are the mole-fraction averages. The viscosity stays that of dry air (Sutherland's law).

No saturation check is made for this input: a mole fraction above the saturation value at the gas temperature describes supersaturated vapour, which the gas model accepts.

Equations

xi=(1−xH2O) xi,dry,M=∑ixiMix_i = (1 - x_{H_2O})\,x_{i,dry}, \qquad M = \sum_i x_i M_i
(1)
wheremeaningunit
xix_iMole fraction of species ii in the humid gas-
xi,dryx_{i,dry}Mole fraction of species ii in dry air-
MMMolar mass of the mixturekg/kmol

Default and rule

Default
0
Rule

0 (dry air).

Source

The mixing rule of the program's gas model; the species data are those used for dry air and exhaust gas.

Valid range 0 to below 1

Typical values

Saturated air holds about 0.023 at 20 °C and 0.57 at 85 °C at 1 atm, less at a higher pressure.